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A Brief Review of the Science and Events at the 11th International
Conference on Cold Fusion (ICCF11)
Scott R. Chubb
Issue 59
Overview of the
Conference
Between October 31 and November 5, 2004, 163
scientists, inventors, engineers, investors, journalists, and reporters
from 21 countries came together, to meet, socialize, and exchange
ideas about Cold Fusion (CF) and Low-Energy Nuclear Reactions (LENR)
in Marseilles, France. This occurred during the 11th International
Conference on Cold Fusion (ICCF11).
The formal program for ICCF11, which
is available on-line at www.iccf11.org, involved "plenary sessions"
and "poster sessions." Plenary sessions took place each
morning and (except for Wednesday, November 3) each afternoon. In
each of them, people who have been involved with the field or who
have suggested potentially useful, new ideas gave invited talks.
On the days when poster sessions were scheduled, information about
each poster was presented through a two step process: 1) Each presenter
was allowed to give a short (three minute) synopsis of the ideas
associated with the poster, at the location where the plenary sessions
were held (and when most of the attendees were present); 2) Later,
the presenter was allowed to discuss the material, using a poster
(which summarized the key ideas), informally, with people who were
interested, at a different location. On the days when these presentations
took place, poster presenters gave their three minute summaries
of their work at the end of each morning, plenary session. The subsequent,
informal discussions took place in a room located next to the auditorium
where the plenary sessions were held, in the late afternoon on November
1 and 4, and immediately before lunch on November 2, in a great
hall located next to the room where lunch was served. On November
3, there were no poster presentations.
On November 2, a special trip was
arranged to Marseilles-Luminy University, where all presentations
took place in a public forum, open to the University community.
(The poster sessions were scheduled at a different time and location
on this day, in order to deal with the logistics associated with
the change in location of the meeting.) In addition to the various
plenary talks and poster presentations during ICCF11, on Wednesday
afternoon and evening, there were three social events: 1) an excursion
to a winery (located at Château dEstoublon) in Provence,
2) a banquet, and 3) a formal reception, hosted by the Deputy Mayor
of Marseilles Daniel Hermann, where Nobel-Laureate Brian Josephson
and co-discover of CF, Martin Fleischmann, were made honorary citizens
of Marseilles. Also present at the ceremony was Dr. Guy Le Lay,
President of the French Physical Society for the Provence area.
Funding for ICCF11 was provided directly
through the conference registration fees paid by attendees and also,
indirectly, through support from Marseilles-Luminy University, the
Center for Condensed Matter Research and Nanoscience (CRMCN-CNRS)
at Marseilles-Luminy University, the data storage company Beemo
Technologies,
the New Energy Foundation, the City of Marseilles, the local department
government (similar to the state government), Des Bouches-Du-Rhone,
and Mediterranean University (Universite de la Mediterranee).
The largest number of ICCF11 participants
from a particular country (39) came from the United States. France
had the second largest number (28), followed by Italy (25), Russia
(16), Japan (13), Germany (8), Israel and the United Kingdom (both
with 6), Switzerland (4), Peoples Republic of China and Nigeria
(both with 3), and Canada (2). The remaining eight participants
came from eight different countries: Australia, Belarus, Finland,
India, Morocco, Netherlands, Spain, and Ukraine.
Besides the social events and scientific
presentations at ICCF11, there were a number of discussions and
presentations related to the political situation associated with
the LENR field. In particular, on Monday afternoon, Mike McKubre
gave an overview of the history and process associated with the
DOEs decision to re-review work related to LENR and the ongoing
review (which has now endedsee story on p. 51).
The International Society of Condensed Matter
Nuclear Science (ISCMNS)
On Monday evening, Akito Takahashi,
Vittorio Violante, William Collis, and I provided an overview of
the history and evolution of a new political/scientific development:
the formation of a new scientific society, the International Society
of Condensed Matter Nuclear Science (www.iscmns.org).
Individuals immediately involved with the ICCF conferences began
to formally suggest that it would be appropriate to create such
an organization in 2002, at ICCF9. Since then, a consensus has been
evolving by scientists within the LENR field that such a step is
both necessary and useful. During the last year, more formal action
has been taken. In particular, during the 5th Asti Workshop and
prior to ICCF11, plans for creating such a society were formalized,
and the associated society (the ISCMNS) held its first formal meeting
in Marseilles, immediately following the presentations by Takahashi,
Violante, Collis, and me.
It is worthwhile to note that as
in the case of a number of other societies, the ISCMNS has been
created to foster both: 1) The dissemination of scientific information
about a particular field; and 2) Increased funding for scientific
research in this field. In order to minimize potential problems
in enlisting support for the new society, the organizers deliberately
decided to select a new name for the Society that seems to appropriately
match the relevant scientific disciplines that appear to be involved,
as opposed to using an alternative name (such as cold fusion) that
not only has failed to represent the relevant science but has (as
a consequence of having been used previously) impaired relevant
scientific discourse.
Through its by-laws, ISCMNS will be required to advance
information about CMNS and, in doing so, to help to advance scientific
interaction in the field and to foster funding of the associated
research. Because of the importance of the ICCF series of conferences
in providing and advancing information about the CMNS field, from
the outset an important goal of the new ISCMNS society has been
to help to ensure that either the ICCF series (and/or a related
series) of conferences will continue, permanently.
In particular, no formal structure has existed for
procuring funding for the ICCF conferences. For this reason, the
process of initiating and organizing one of these conferences has
always entailed a degree of financial risk. Although historically,
during the initial stages of the CF controversy, institutions (like
the National Cold Fusion Institute, or the Electric Power Research
Institute, for example) provided the necessary financial backing
to help alleviate the associated risk, more recently comparable
institutional support has not existed. As a consequence, beginning
with ICCF9, the process of initiating an ICCF conference has involved
a considerable financial burden (and potential liability) that has
usually been undertaken by a single personthe ICCF conference
chairman. By providing institutional support, the ISCMNS will help
to alleviate these kinds of financial responsibilities. (This process
has already begun: During ICCF11, ISCMNS contributed several thousand
Euros to the conference.)
It is also worthwhile noting that the ISCMNS almost
certainly will provide funding for other conferences. In particular,
the leadership of the ISCMNS anticipates that funding will be provided
to the Asti series of workshops (on Anomalies in Hydrogen/Deuterium-Loaded
Metals), which have been held approximately once every 15 months
since 1997. Also, as president of the ISCMNS and chairman of the
Japanese Coherent Fusion Research Society (JCFRS),
Akito Takahashi will be playing important roles in both organizations.
The organizers of ICCF11 and ISCMNS believe that the dual role that
Professor Takahashi will be playing in both organizations will help
to facilitate support for the annual JCFRS meetings that take place
in Japan. Potentially, similar support could be provided for the
Sochi Conferences that are held in Russia (which have been held
every year since 1990) and possibly in helping individuals to attend
cold fusion sessions at meetings in the U.S. (for example, sessions
of the American Physical Society and American Nuclear Society).
Talks Related to the Politics, Sociology,
and History of LENR
A number of presentations associated with the politics,
sociology, and history of the LENR field were presented on Thursday
and Friday. These included talks by Jed Rothwell ("Cold Fusion
and the Future"download the e-book at http://lenr-canr.org/acrobat/RothwellJcoldfusiona.pdf)
and Gustav Grob ("The International Sustainable Energy Organization
and Novel Energy Systems"), on Thursday afternoon, and Brian
Josephsons Friday morning talk, "Good Ways and Bad Ways
to Do Science." This last talk was especially memorable. In
it, Professor Josephson gave a detailed account of his failed attempts
to have a cold fusion paper (by Edmund Storms) accepted for publication
in the Cornell e-print archive (xxx.arxiv.org). He also discussed
other instances in which authority figures in science have denied
scientists involved in controversial areas of research (including
extra-sensory perception, and cold fusion, in general terms) the
privilege of having their work published, based on entirely unscientific
and (at times) unethical reasons.
Additional Information and Availability of
the Conference Proceedings
Most of the more important papers were presented in
the plenary sessions. Some of this material (as well as additional
material from a number of the posters) is available in electronic
form online at www.iccf11.org/
and at www.iscmns.org/iccf11/iccf11.htm.
By becoming a member of ISCMNS (through the www.iscmns.org website),
it is also possible to purchase a CD that contains additional material
that is not available to the general public. The ICCF11 Conference
Proceedings papers, as they are received, will be made available
at www.lenr-canr.org.
Formal publication of the Proceedings will be through a written,
hard-copy, which will also be available in electronic form through
links at the www.iscmns.org
and www.iccf11.org
sites.
ICCF12 has been scheduled for November 27 through
December 2, 2005 in Atami, Japan.
Overview of Important Papers and New
Science Presented at ICCF11
General Comments:
Two important questions that have not been examined
in detail at ICCF conferences in the past are: 1) The potential
role of structural changes inside and on the surface of pieces of
metal where reactions take place in (most) LENR experiments, and
how by pre-treating candidate pieces of metal (for subsequent experiments),
using particular procedures, it might be possible to alter the structure
of these substrate materials in ways, consistent with observation,
that potentially can promote LENR; and 2) Questions related to whether
or not substrates are even necessary in order to initiate LENR.
The first question relates to a potential way of understanding the
role of structural change in the underlying phenomena. In particular,
although structural changes have been monitored, for example, using
Scanning Electron Microscopy (SEM) and related techniques, in CF
experiments, systematic attempts have not been undertaken to create
the kinds of structures that have been found to be helpful, based
on the use of simulations and a knowledge of the relevant material
science, previously. The second question, which is seemingly completely
at odds with the first, is related to a more general question: Which
forms of LENR are related to each other? Can certain forms of LENR
(which had been thought to be related to particular environmental
factors, such as those that involve material substrates where the
particular reactions are thought to take place) be initiated in
entirely new situations in which substrates (and potentially other
structures) are not present? Both series of questions, ultimately,
are related to an important development at ICCF11: The beginning
of a systematic approach for isolating relevant from irrelevant
factors in particular LENR experiments.
New strategies and procedures, associated with the
first question, that were discussed included attempts to isolate
and determine the role of particular structural features, both in
excess heat experiments and in investigations of transmutation.
(Transmutation refers to a process in which new elements appear
to be created at room temperature through low-energy nuclear reactions.)
An important potential goal of these kinds of studies is to identify
ways to create patterns associated with changes in the microscopic
structure of the materials that appear to be helpful in initiating
the new phenomena. The hope is that this will result in a more precise
microscopic understanding of the associated effect(s). One important,
motivating factor for following this procedure is that fairly crude
effects, associated with loading (and how to achieve loading) in
the excess heat experiments, can be related systematically to forms
of pre-treatment of the associated materials. At a more basic level,
although this kind of approach has only been applied in a few situations,
it appears to have had a real impact on new experiments. The underlying
strategy for treating particular (potentially active) substrate
materials clearly is better than the alternative, hit-or-miss procedure
(in which a particular material is selected arbitrarily), that has
been commonly used in the past. An additional important theme, reported
by several groups at ICCF11, involved the development of new and
improved procedures for triggering excess heat, in a reproducible
fashion, either through variations in the way that the external
source of heavy water strikes the material substrate (where the
reaction takes place), or by using externally applied electric and/or
magnetic fields, either directly in D.C. form (in the case of electric
fields) or (in a situation in which both magnetic and electric fields
are present) using optical forms of excitation, using lasers.
Finally, it is worthwhile noting that considerable
(perhaps too much) attention was placed on transmutation (as opposed
to excess heat or particle emission) experiments. Part of the reason
for this is that a number of people who have done important work
related to excess heat and particle emission were unable to attend.
In particular, because of an unfortunate scheduling conflict, Yoshiaka
Arata was not able to come to ICCF11 (despite the fact that he was
initially scheduled to give an invited talk) because at the time
of the conference he was scheduled to receive an important award
(a medal that was presented to him by the Emperor of Japan). Other
experts in excess heat who were not present were Mitchell Swartz
(who also had been scheduled to give an invited talk), Melvin Miles,
and Antonella De Ninno. Although a small number of particle emission
talks were presented (by J. Kasagi, A. Lipson, R. Oriani, T. Mizuno,
L. Kowalski), several individuals (most notably Steven Jones) who
have been involved with this kind of work also were not present
at ICCF11.
Important Excess Heat Experiments:
Although a relatively small number of people spoke
about excess heat, three talks related to this topic not only were
noteworthy, but, in one case, the associated presentation (by Roger
Stringham, of First Gate Energies, P.O. Box 1230, Kilauea, HI 96754)
potentially will be remembered as being as (if not more) important
as any other talk that has ever been given at any ICCF conference.
Stringhams talk was significant because in it, he described
a breakthrough (associated with significantly reducing the size
of his sonofusion device) that could lead to a significant development
in the field: The potential for controlling and sustaining excess
heat, through a process which is initiated with a form of power
that can be scaled upwards. In particular, it is quite possible
as a result of this breakthrough that real devices (for producing
heat) will be developed within the next several years.
A key point is that Stringham uses a procedure (that
involves cavitation) for loading the substrate material (a piece
of Pd metal, for example), where the reaction takes place that is
considerably more robust than the more commonly used procedures
(associated with electrolytic- and gas-loading) for creating excess
heat. Stringhams procedure is more robust because it is based
on a dynamic process (in which bubbles of heavy water implode into
a metal target, in a highly non-equilibrium fashion at high velocity).
Not only is the associated loading rapid, as a consequence the triggering
process appears to be considerably more useful for potential device
applications than other potential triggering processes: In particular,
Stringham has been able to trigger heat production not only in Pd,
but in a number of other materials.
Beginning with the cover story of the very first issue,
Infinite Energy has provided detailed descriptions of Stringhams
cavitation procedure (Tom Benson, 1995. "A Micro-fusion
Reactor: Nuclear Reactions in the cold by Ultrasonic
Cavitation," IE, 1, 1, 33; Roger Stringham, 1998. "Cavitation
in D2O with Metal Targets Produces Predictable Excess
Heat," IE, 4, 19, 41). Because of Stringhams earlier
successes, an effort was undertaken by the New Energy Research Laboratory
(NERL) to reproduce the associated effect. Although the staff scientist
responsible for this effort, Ken Rauen, initially thought he had
reproduced the effect (Ken Rauen and Eugene Mallove, 2001. "First
Gate Energies Sonofusion Reactor: Initial Validation
at 50% Excess Heat," IE, 6, 36, 18), he subsequently
found that the calorimeter calibration that he had used in his measurements
had drifted during the experiment, and, in fact, he did not find
any excess heat (Ken Rauen and Eugene Mallove, 2001. "Sonofusion
Calorimetry," IE, 6, 37, 39).
An important step in Stringhams earlier procedure
is associated with placing the metal target at a particular (optimal)
location. It is plausible that the NERL experiments did not create
excess heat because the locations of the targets in Rauens
and Stringhams experiments were not the same. In particular,
in Stringhams procedure, excess heat is initiated when bubbles
of heavy water implode in a very specific way, in the immediate
vicinity of a particular piece of metal (the metal target). The
bubbles are produced using ultrasonic waves that are allowed to
propagate inside a cavity, containing heavy water. When the frequency
of the waves and the size of the cavity are selected in an appropriate
way, standing waves can form, as a result of constructive and destructive
interference between traveling waves that propagate in the (forward)
direction across the cavity with reflected waves that travel in
the reverse (backward) direction. (The reflected waves result when
waves that are traveling in the forward direction bounce off the
forward boundary of the cavity.)
When the associated standing waves collide with materials
that are placed in the cavity, at particular locations, extremely
rapidly imploding bubbles can be created. In certain circumstances,
the associated bubbles can inject heavy water into the metal target
with such high momentum that locally, high loading can take place,
and heating from a CF reaction is initiated. (The sonofusion reactions,
like the CF reactions that take place in the more conventional electrolytic
CF cell configurations, do not produce neutrons or high energy particles,
and the primary heat-producing reaction creates 4He.)
At ICCF11, Stringham reported significant progress
in controlling, sustaining, and reproducing heat from sonofusion
reactions, as a result of dramatically increasing the frequency
(by a factor of 40) of the ultrasound that is used to produce the
standing waves, while reducing the length of the cavity (by roughly
a factor of 40). The new design operates with an ultrasonic frequency
of 1.6 MHz, using piezoelectric elements that are the size of a
quarter. One module weighs 20 grams. The power density of these
modules is 2 watts/gm and about 10 watts/cc.
Plausible reasons for the success of the new design
are associated both with constraining the waves to a smaller volume
and the increase in frequency. In particular, although historically
in the larger devices previously developed by Stringham an important
limiting factor associated with initiating the CF reactions involved
identifying the optimal position for placing the metal target, apparently,
it is considerably easier in the new (smaller) cavity to identify
and optimally select the comparable location. Typically, in the
new geometry, Stringham can create 40 net watts (W) of excess power,
using input power of approximately 40 W. Although the net excess
heat is insufficient in amount to produce enough electricity to
sustain the process indefinitely without an outside source of power,
the efficiency for producing heat (which is ~150-200%) in this device
is considerably higher than in an any existing form of heat generator.
A potentially important point is that because each
sonofusion device, in the present architecture, is compact in size,
and the associated heat can be produced at elevated temperature,
it is entirely reasonable to assume that a number of heat-producing
devices based on the present design can be used together to create
heat in a scalable fashion.
Stringhams work is also important because it
involves a procedure for forcing deuterium (D) atoms into the metal
that is not implicitly limited by a number of the physical factors
(associated with temperature and/or pressure) that occur in the
alternative, electrolytic- and/or gas-loading, procedures that are
frequently employed.
A second group, from IsraelEnergetics, Ltd.has
developed a new loading technique that apparently also can be used
to create excess heat in a reproducible fashion. The innovative
step in their work, that appears to make this possible, also involves
using waves. As opposed to using standing waves, however, the Israeli
group uses an entirely different procedure for loading and triggering
excess heat. In particular, Arik El-Boher, of Energetics, explained
that in their work, a non-linear, superposition of different waves,
involving many different frequencies, is constructed and used to
force D into a Pd substrate electrolytically or (in glow-discharge
experiments) in an ionized, gaseous form (which is created by passing
currents through a D+ plasma), into a Pd metal substrate. The associated
waves (which El-Boher refers to as "Super-Waves") impart
momentum to the heavy water (D+ plasma) in the electrolytic (glow-discharge)
experiments, in a time-dependent manner that includes many different
frequency components. Empirically, the Israeli group has found the
"Super-Waves" appear to induce considerable variations
in loading, and it is possible to obtain high loading in tens of
seconds electrolytically (as opposed to loading times of tens to
hundreds of hours that are frequently required in more conventional,
electrolytic procedures). In the electrolytic experiments, the Israeli
group also reported large amounts of excess power (in which output
power is as much as 25 times larger than input power), and the phenomenon
of "heat after death" (in which excess power continues,
in the absence of an electrolyte). Al-Boher also reported that they
had found tritium in one of their electrolytic experiments.
Energetics, Ltd. only entered the LENR field recently.
(The first presentation by anyone from Energetics at an LENR conference
took place during ICCF10, in 2003.) But this company not only is
well-funded, it has quickly established one of the more important
groups studying excess heat. In their recent electrolytic work,
they have been using electrodes that were provided by a second group,
which not only is also well-funded but is one of the more important
(if not the most important) research centers involved with investigating
excess heat: the group from ENEA (Italian National Agency for New
Technologies, Energy, and the Environment), located in Frascati,
Italy.
Underlying much of the successful effort at ENEA for
creating excess heat (which they claim they are now able to produce
100% of the time, provided particular criteria are satisfied) is
a research strategy that is based on the assumption that it is necessary
to understand important attributes of the materials (and the associated
material science) in order to reproduce the associated effect. For
this reason, at ENEA scientists have performed detailed analyses
of the material properties and structure of the electrode materials
that are used in their experiments.
Vittorio Violante, who is the senior scientist associated
with the work, described these efforts in detail. The associated
analysis and measurements are being carried out at the official
ENEA Cold Fusion Laboratory. (Energetics obtained at least one of
its electrodes from the Frascati group.) In particular, Violante
emphasized that to reproducibly generate excess heat, it is necessary
to understand the conditions for reproducibly achieving high loading.
He also emphasized that the conditions for achieving high loading
in deuterated metals: 1) Are controlled by equilibrium and non-equilibrium
phenomena; and 2) Are impeded by self-induced stress, resulting
from concentration gradients in deuterium at the surface, during
loading, which can significantly reduce deuterium solubility and,
as a consequence, reduce loading. A major focus of the ENEA materials
research effort has been to identify procedures (for example, annealing
and cold-working the materials at particular temperatures) for minimizing
self-induced stress.
Violante then described the initial (closed
cell) calorimetric procedures, helium measurements (which the ENEA
team performs, in situ, along with measurements of heat).
During nine experiments, in which loading values (the values of
x in compounds of the form PdDx) exceeded 0.9, they obtained excess
heat only twice. This suggested that, although necessary, high-loading
is not sufficient for producing excess heat. Faced with this problem,
they searched for a potential triggering mechanism.
Similar to results obtained by other groups, and reported
during ICCF10, they found they can trigger excess heat by optically
irradiating their electrodes with a laser, at relatively low (33
mW) power, tuned to a particular (.635 micron) frequency. (They
also alternately switched the current [and loading] between higher
and lower values.) After applying these stimuli, they were able
to obtain excess heat, each time, during each of three experiments.
They also found that the amount of extra 4He and excess
heat in each of these experiments is consistent with a result found
at SRI (and elsewhere): That the amount of additional (excess) heat
energy that is observed equals one-to-two times the amount of energy
that results from the product of the total number of additional
4He atoms that are observed outside the electrode with
the energy release (23.8 MeV) that would occur if all of the energy
associated with the d + d
4He fusion reaction is converted directly into heat.
(At SRI, Mike McKubre and his co-workers have shown that, depending
on the material properties of the electrodes that are used in electrolytic
experiments, the excess heat can be expected to be larger than the
amount associated with 4He found outside the electrode,
because an approximately comparable amount of 4He can
be expected to remain trapped inside the cathode.)
Important Transmutation Presentations
Beginning at ICCF9, and continuing through ICCF10,
Yasuhiro Iwamura from Mitsubishi Heavy Industries discussed remarkable
results, which have appeared in a refereed journal (Jpn. J. Appl.
Phys., 2002, Vol. 41, pp. 4642-4650), associated with the possibility
of what appears to be a form of novel transmutation in which four
deuterons combine with nuclei from a material (Sr or Cs) that has
been electroplated onto a particular substrate, consisting of Pd
and CaO layers that are interspersed in a very specific structure.
When Sr is electroplated onto the substrate, and placed under 1
atmosphere of D2 gas, after several hours, effectively,
a reaction of the form Sr + 4d
Mo appears to have taken place. (Here, d refers to a deuteron.)
When Cs is electroplated onto the substrate, the effective reaction
is of the form Cs + 4d Pr.
One reason that the Iwamura et al. work is
so important is that the procedure involves a very well-instrumented
experiment, in which the material composition of the substrate is
very specific, and the manner in which loading takes place is systematically
controlled. (In particular, the amounts of D2 gas are
systematically increased and decreased, and the amounts of particular
atoms, found at the surface of the substrate, are carefully monitored,
using X-ray photoemission measurements.) For this reason, as opposed
to situations (involving electrolysis or other forms of loading)
in which surface chemistry and morphology can become quite complicated,
the underlying dynamics (at least superficially) in the Iwamura
et al. experiments appear to be considerably simpler, and
the underlying process can be monitored using precise measurements
of potential changes of the materials that are associated with possible
nuclear reactions. Thus, for example, in this work, the behavior
and control of the materials at the surface of the substrate is
tightly constrained. Two additional reasons that the Iwamura et
al. work is important are: 1) Because the end-product, praseodymium
(Pr), in the Cs + 4d Pr
reaction is so rare, how it could appear at all (for example, through
some form of transport process), except through a nuclear reaction,
is difficult to explain; and 2) A subsequent analysis of the distribution
of isotopes, that are present in the Mo end-product (in the Sr +
4d Mo reaction), which
is very different from the distribution that occurs naturally, matches
the distribution that results when it is assumed that in each reaction,
four deuterons are added to the nucleus of an Sr atom (associated
with one of its naturally-occurring isotopes), and the distribution
of Sr isotopes found initially after electroplating approximately
matches the one that occurs naturally.
During ICCF11, after reviewing the initial experiments,
Iwamura described new results that indicate a new form of transmutation
in which two forms of Barium (137Ba and 138Ba)
appear to be converted into the comparable forms of samarium (149Sm
and 150Sm) that would result when six protons and six
neutrons (six deuterons) are added to each Ba nucleus. He then described
additional work, associated with a further validation that Pr is
being created (from Cs), using an improved (tunable) X-ray source
(the Spring-8 synchrotron). Using this alternative source, the Mitsubishi
team used X-ray fluorescence measurements to further quantify that
Pr is present. These measurements also provide evidence that the
associated effect (involving the possible transmutation of Cs into
Pr) is not related in some way (possibly through some form of collective
excitation, triggered by the X-ray source, used in the initial X-ray
photoemission experiments) to the use of a particular X-ray source.
Iwamura also discussed work that they performed in
addressing one question that has remained unanswered in their work:
The role of a particular composite material (involving thin films
of CaO interspersed between thin films of Pd) that is used as part
of the substrate that holds the films (of Cs, Sr, or Ba) that are
formed during the electroplating process. In particular, a schematic
diagram of the substrate that is used in these experiments is shown
in Figure 1. It consists of a sandwich-like structure, in which
a moderately thin (0.1 ) film
of a form of composite material (involving interspersed layers of
CaO and Pd) is sandwiched between a thinner (.04 )
film of Pd and a second, relatively thick (.1 ) film of Pd. Iwamura
reported that the apparent transmutation process does not take place
when the CaO layers are replaced with MgO layers. Using (D+) ion
implantation and ion bombardment facilities at Tokohu University,
Iwamura also reported that the Mitsubishi group performed measurements
of the effective screening potential (during ion bombardment) using
the composite (CaO/Pd) material and pure Pd. They inferred from
these measurements that the density of implanted D in the composite
(CaO/Pd) material is roughly an order of magnitude greater than
the density of implanted D in Pd.

Figure
1. Schematic diagram of
the "sandwich structure" that the Mitsubishi group uses in the
design of their electrodes. As explained in the text, the structure
consists of three films: a thin (0.04 ) film of Pd, on top of a slightly thicker
(0.1 ) film of a composite
(CaO/Pd) material (containing thin films of CaO interspersed
between thin films of Pd), on top of a thick (0.1 ) film of
Pd.
In a truly remarkable and significant talk, Pamela
Mosier-Boss described a number of experiments that she, Stanislaw
Szpak, and Frank Gordon have conducted at the Space Warfare System
Center, in San Diego, California. In their work, Pd is deposited
in the presence of evolving D2. In the past, they have
reported numerous results, including the emission of low intensity
radiation (Physics Letters A, 1996, Vol. 210, pp. 382-390),
tritium production (Fusion Technology, 1998, Vol. 33, pp.
38-51), excess heat generation (Thermochimica Acta, 2004,
Vol. 410, pp. 101-107), and formation of "hot spots" (Il
Nuovo Cimento, 1999, Vol. 112A, pp. 577-585). Three important
features of their procedure are: 1) Short loading timesmeasurable
effects are found within minutes; 2) Extremely high repeatability;
and 3) As a result of their loading procedure, any potential reactions
associated with their procedure are localized in surface regions,
where the co-deposition of Pd and D takes place. As a consequence,
their procedure is extremely flexible and can be adapted so that
multiple electrode surfaces can be used in different geometries.
Because the experiments are repeatable and fast, many variables
and parameters can be checked.
Because the reactions are localized in the surface,
probes of surface morphology (in particular, SEM pictures) can be
extremely useful for understanding structural changes that may be
important in potential LENR. Also, as a consequence of the reactions
being localized in the surface environment, implicit forms of anisotropy
are present that can help to amplify or cause particular changes
in structure to occur, as a result of externally applied fields,
that may be relevant in producing LENR, in a manner that can be
identified using probes of changes in surface morphology, like SEM
images.
During ICCF11, Pamela Mosier-Boss described a new
set of experiments in which probes of surface morphology and the
application of external (electric fields) were used to produce and
identify particular structures that subsequently were found to contain
materials (Ca, Al, SI, Mg, and Zn) that (because of their distribution)
she suggested probably were the result of transmutations. Although
the associated argument is not conclusive, the evidence is provocative.
An important point is that the approach that Pamela
Mosier-Boss and her colleagues have adopted marries techniques associated
with identifying particular changes in microstructure with procedures
for altering microstructure, using a system (created by their codeposition
technique), where it is possible to systematically alter a set of
parameters associated with an externally-applied (electric) field
that appears to trigger some form of transmutation. To my knowledge,
this is the first time an attempt has been made to identify the
relationship between changes in microstructure that might be related
to potential LENR transmutations, that can also be induced, using
applied fields, in an environment in which the conditions associated
with a particular form of LENR can be reproduced, on demand. Because
the external fields that potentially can trigger the effect can
be changed systematically, potentially the associated procedure
can be used to study the relationship between changes in microscopic
structure and LENR.
A second group (from STMicroelectronics, via Tolomeo,
1 200010 Cornaredo, Milano-Italy) has been conducting experiments
in which attempts are made to understand how possible transmutations
might be related to changes in microstructure that are triggered
by externally applied fields. U. Mastromatteo described the associated
effort. In their experiments, initially, samples of silicon that
are coated with a thin Pd layer are implanted with phosphorus ions.
Then, the resulting structures are exposed to deuterium or hydrogen
gas and irradiated with excimer laser beams. SEM images are constructed
of the resulting structures, followed by an analysis of their material
composition. Although the results of this work are preliminary,
as in the Pamela Mosier-Boss et al. work, the procedure that
is used possibly can lead to more systematic studies in which changes
in microstructure are related to potential nuclear transmutations.
Particle Emission Studies:
J. Kasagi discussed new results associated with Li+D
reactions in Pd and Au (Kasagi et al., J. Phys. Soc. Jpn.,
2004, 73, 608), at lower (~1 KeV) energies than those that are used
in most, conventional nuclear experiments. He began by providing
some background about his previous work involving D+D reactions
in metals. In particular, he previously found that the D+D nuclear
fusion reaction rate in metals can be strongly enhanced, in some
cases, as much as ~100 times larger at incident, kinetic energies
of ~1 KeV. The enhancement implies a considerably larger screening
energy than would be expected, as much as several hundreds of eV.
He suggested that this extrapolation (assuming the
standard Gamow tunneling model is applicable) to the larger screening
energies implies that in the limit of vanishing incident kinetic
energy, fusion rates could be as large as to 109/cc/sec.
His motivation for investigating D+Li (as opposed to D+D) was to
see how the presence of a target (Li) with a higher atomic number
in the metal would alter the screening energy. He found that when
D ions bombard Pd-Li or Au-Li alloys, the Li+D screening energy
was significantly enhanced, as in the D+D case, but he has been
able to perform the extrapolation (and scaling) only qualitatively.
He also used the same technique to measure screening energy as a
function of incident kinetic energy when D ions bombard a liquid
or solid Li target. Here, he found clear evidence of an effect associated
with the phase change from liquid to solid that might enhance the
reaction rate at lower energies.
Richard Oriani and John Fisher presented data from
CR-39 track detectors that indicate MeV alpha particles are present
(outside the walls that surround cells, in which normal and heavy
water are being electrolyzed by Ni and Pd cathodes) where, arguably,
their existence (based on standard rules, associated with particle
penetration) can not logically be related to potential nuclear activity
within either the Ni or Pd cathode. Considerable interest in the
associated phenomena has resulted. In a series of measurements performed
by Ludwik Kowalski, similar alpha particle tracks were observed
above inactive electrodes. A. Lipson and A. Roussetski presented
a talk in which they reviewed the procedures for using CR-39 detectors.
T. Mizuno also presented evidence for potentially
novel forms of particle (in this case neutron) emission from D2
gas in a magnetic field. In his talk about this possibility, he
also reviewed his previous transmutation results (in glow-discharge
experiments), as well as his earlier neutron emission work. An interesting,
and potentially useful, idea that he suggested in this particular
talk involves simplifying the environment associated with a potential
LENR by distinguishing effects (for example, from substrates) that
might appear to be relevant (but possibly are not) from other effects.
Additional Comments
As I said in my general comments used to introduce
my overview of the scientific papers, there were many papers about
transmutation at ICCF11. Given the past history of the field, I
have learned to be open-minded. In particular, for example, in 2000,
I certainly would never have believed that the kinds of results
that have been observed by Iwamura and his colleagues were possible.
In my assessment, I deliberately have not provided details about
many of these ideas, partly because, given my own biases, I do not
think I would be capable of providing an objective appraisal. Instead
of attempting to do this, I have deliberately focused on the experiments
and results, in the case of transmutations, that appear to be most
mature and testable.
Deliberately, for similar reasons, in this review,
I have discussed particular experiments and results associated with
excess heat and particle emission that I feel are more mature than
others. Again because of personal biases, I have not discussed work
in my own area of expertise: the theory of LENR. I would like to
acknowledge my appreciation for being able to interact with a number
of theorists at ICCF11, including my good friends Peter Hagelstein,
Robert Bass, Xing Zhong Li, and Yeong Kim. I also especially enjoyed
being able to spend additional time (well beyond the usual amount)
interacting and arguing with my uncle, Talbot Chubb, about his and
my ideas. Finally, I would like to mention how much I thoroughly
enjoyed interacting with a newcomer to LENR theory: Dr. Julian Brown.
His ideas and enthusiasm are a refreshing and inspiring change that
certainly will help to advance further theoretical work and meaningful
discourse.
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